When the U.S. phased out PFOA, long used to make Teflon, China's production and use of the toxic chemical soared.











Standing on a concrete bridge above the Xiaoqing River, a farmer named Wu shook his head as he gazed down at the water below. Wu, who is 61, used to be able to see all the way to the bottom. And he and others in Cuijia, a village of about 2,000 in China’s Shandong province, used to swim at this very spot. There were so many turtles he could easily stab one with his forked spear, he recalled on a steamy Saturday in July. To catch some of the many fish, he simply threw a net into the water, he said, moving his arms as he spoke in a gesture that has survived in his muscle memory long after most of the fish have disappeared.
The Xiaoqing flows 134 miles through the major cities of Zibo, Binzhou, and Dongying in Shandong province. Tens of millions of people depend on it. In Jinan, which is close to the river’s origin, human and livestock waste and runoff from fertilizers and pesticides have caused the water to stink in recent years. But downstream from Jinan, waste from factories has compounded the river’s problems.
Directly translated from Chinese, the word “Xiaoqing” means “clean and clear.” But here in Cuijia, the water is neither. From the bridge, you can see debris and garbage swirling atop the forceful rush of brown. Occasionally, bits of plastic and something that looks like Styrofoam float by. But what may be most dangerous in the Xiaoqing River isn’t visible: perfluorooctanoic acid, or PFOA, long used by DuPont in the production of Teflon, among other products, and linked to cancer and other diseases. Because Cuijia lies downstream from a factory that emits more PFOA than any other industrial facility in the world, levels of the chemical at various points near here are among the highest ever reported, reaching more than 500 times the safety level the U.S. Environmental Protection Agency recently set for drinking water. The plant, operated by a company called Dongyue Group, is the world’s biggest producer of Teflon and emits 350 pounds of PFOA every day, an amount that totals 63 tons in a single year, according to a recent estimate.
DuPont and seven other companies agreed to phase out the use and production of PFOA in the United States by 2015, after lawsuits and protracted negotiations with the EPA. Keeping toxic chemicals at bay in countries that have relatively strong environmental regulations is a Herculean task that, in the case of PFOA and perfluorooctane sulfonate, or PFOS, is still underway. Though this effort can consume the energies of Western environmentalists, the story doesn’t end when they push a toxic chemical beyond their borders. In China, that’s often when a chemical’s life begins in earnest.
As we stood next to the river, Wu looked out across the landscape. He wore blue plastic sandals and baggy gray pants. A shovel, from which two empty plastic buckets hung, lay across his shoulders, and as he listened to translations of my questions he nodded slightly. He had never heard of PFOA, he said, and didn’t know the exact causes of his village’s problems. There may be many. The Dongyue plant isn’t the only factory that disposes of its waste in the water. Wu said a paper mill upstream also puts waste into the river. And Dongyue itself makes many chemicals in addition to PFOA.
But Wu understands well that something has profoundly changed the river he has relied on his whole life. For more than a decade, the people of Cuijia have watched as their crops have stopped thriving. The corn does better than the wheat, he said, but both have become harder to cultivate. Recently, his wheat crop failed altogether, imperiling his family’s meager income.
Then there’s the sickness. More and more people in Cuijia have been falling ill and dying, he said, often with cancer and at a young age. When I asked whether any of them got medical help or reimbursement for their doctors’ bills when they became sick, Wu guffawed theatrically, putting one hand over his belly and turning his face to the side, as if some invisible presence would appreciate the absurdity of my idea. After his laughter subsided, he explained that some of the villagers had recently reported the increase in pollution and cancer to the local government, but had received no response.
In 2005, a class-action suit against DuPont over contamination in West Virginia and Ohio set off the first alarms about PFOA, also known as C8 because of its 8-carbon molecule. In the intervening years, the attorney overseeing that case has waged a campaign to get the government to regulate the chemical in the U.S. But until recently, concern about perfluorinated compounds, or PFCs, in the U.S. remained the preoccupation of a small group of scientists and legal experts. It was only in the past year, as PFOS from firefighting foam was discovered in the water near hundreds of military bases, and communities around the country found PFOA and other PFCs in their drinking water, that awareness blossomed into outrage.Around the world — from Hoosick Falls, New York, to Buck’s County, Pennsylvania, Holland, Sweden, and several parts of Australia — communities have begun to understand not only that the chemicals have been in their water for years but also that the contamination continued after industry scientists knew PFOA and PFOS persisted indefinitely in the environment, accumulated in human bodies, and affected health.
Yet by the time that information made its way to the public, the contamination was too great to be completely cleaned up, and PFCs were already in the vast majority of human bodies. A 2007 study by researchers at the Centers for Disease Control found that 99.7 percent of Americans over 12 had trace amounts of PFOA in their blood, while 99.9 percent had PFOS. The contamination begins even before birth, according to a 2006 study, which detected PFOA in 99.3 percent of umbilical cord blood.
Workers repairing a sluice on the Zhulong River fish on the Xiaoqing River during their lunch break. One worker said, “These little fish can take a lot. Ordinary pollution won’t kill them.”
Photo: Jiang Mei for ChinaFile/The Intercept
This mounting knowledge has translated into action in many places — if slowly and, some argue, inadequately. The European Union officially deemed PFOA a “substance of very high concern” in 2013, a designation reserved for chemicals that have “serious and often irreversible effects on human health and the environment.” Production and use of both chemicals has subsequently ceased throughout most of Europe, Japan, and Canada. And in response to outrage over contamination, one Australian state recently banned firefighting foam that contains PFOS.
In the U.S., an agreement between the chemical industry and the EPA brought all production and use of PFOA and PFOS to an end last year. And in May, in part because of concern in communities that had discovered PFOA and PFOS in their water supplies, the EPA came up with voluntary standards limiting the amount of both chemicals in drinking water to .07 parts per billion (ppb). This week, New Jersey’s Drinking Water Quality Institute recommended a much lower standard, .014 ppb, one-fifth that of the federal EPA. The U.S. Air Force just announced that it would replace its PFOS-containing firefighting foam with a safer substitute, and people exposed to the chemicals in their water have sued both the U.S. Navy and private companies.
Yet while most of the world was phasing out PFOA and PFOS and beginning to address the problems they had caused, the chemicals emerged in countries with fewer restrictions. There is some evidence that India and Russia have recently used PFOA to make Teflon and that Russia may also be manufacturing the chemical. But it’s in China that the business has truly boomed, keeping global output of PFOA and PFOS steady even as the industry ground to a virtual halt everywhere else.
China is now the world’s biggest source of both PFOA and PFOS. Between 2004 and 2012, as the West was scaling down its PFOA production, China’s production and emissions roughly tripled, according to one 2015 study. Though it’s impossible to quantify precisely, the country now makes somewhere between 64 and 292 tons of PFOA per year, most of which is released directly into the water and air. Total PFOA emissions in China may be as high as 168 tons per year, according to one recent estimate. And both production and emissions are predicted to continue through at least 2030. China also produces somewhere between 110 and 220 tons of PFOS a year, more than any other country.So while Teflon began as a quintessentially American brand, China now manufactures most of the world’s supply of the slippery substance, which is used in dental floss, textile fibers, wire and cable insulation, and hundreds of other products, including nonstick cookware. The Dongyue plant in Shandong used PFOA to make more than 49,000 tons of Teflon in 2013 as well as four other products, including PVDF, a compound used in the semiconductor, medical, and defense industries.
Though they’re toxic, persistent, and accumulate in human bodies, PFOA and PFOS are by no means the only contaminants China has to worry about — or the most dangerous. Heavy metals such as lead, mercury, arsenic, and cadmium, which cause cancer, lung problems, and brain damage, have made one-fifth of the country’s farmland too polluted for growing food. Air pollution, which has reached hazardous levels in at least 83 cities — and in some places, as much as 20 times recommended levels — is perhaps the country’s most visible problem and is contributing to soaring lung cancer rates.
The nation’s water crisis is just as dire. More than 80 percent of China’s underground water supply is unfit for human consumption and almost two-thirds is unfit for any human contact, according to a government report released earlier this year. Some 300 million people —almost equivalent to the entire U.S. population — lack access to clean drinking water, and an estimated 190 million have become sick from drinking water polluted with everything from pesticides to heavy metals, toxic waste, and oil spills.
If PFCs aren’t China’s most pressing environmental problem, they are the most pronounced example of a global pattern that helps explain how the country came to be one of the most polluted in the world.PFOA and PFOS are just the latest in a steady stream of chemicals to make the journey to China after being cast off by countries that have deemed them unacceptably hazardous. Production of short-chain chlorinated paraffins, which are used as lubricants and coolants in metal cutting, shot up 30-fold in China as these chemicals were coming under EPA scrutiny. Similarly, China is now the world’s biggest producer of HBCD, a flame retardant the EPA recently targeted for action. And the aniline dye industry migrated from the U.S. to China after it was well established that the chemicals involved are carcinogenic.
“I call it the leftovers problem,” said Joe DiGangi, who works for IPEN, a network of organizations in 116 countries devoted to protecting health and the environment from toxic chemicals. “Often a chemical comes under public or regulatory pressure in the EU or the U.S. and then shortly thereafter, Chinese companies begin producing it,” said DiGangi. China and the other developing countries that inherit it, he said, “often don’t have the adequate infrastructure to regulate, monitor, and deal with it safely.”
This global migration of toxic chemicals across borders can help explain why the Changshu Advanced Materials Industrial Park sprang up in 2001, just as the first suit over PFOA contamination in West Virginia was being filed and PFCs were coming under the scrutiny of the EPA. Originally named the Chiangsu High-Tech Fluorine Chemical Industrial Park, the almost 6-square-mile campus in the Yangtze River Delta is home to more than 40 factories. With an output of 31,000 tons per year, it is China’s second largest source of Teflon after the Dongyue plant. Many of the factories in the park produce fluorochemicals, and several of them are operated by companies that used or made PFOA and PFOS in the U.S. until recently, such as Solvay Solexis, Arkema, and Daikin. (Solvay Solexis, Arkema, and Daikin did not respond to requests for comment.)DuPont, which made Teflon a household name, also built a plant here in 2008 at a cost of $80 million. In July 2015, it passed the facility on to a new company called Chemours, when it spun off its performance chemical division. In July 2016, Chemours announced it would invest $15 million to expand its Changshu Works plant to augment the company’s “already considerable presence in China” and increase Teflon output. (Chemours did not respond to multiple requests for comment.)
With its own fire station and heat, water, power, sewage, and postal systems, the Changshu industrial center is like a small self-contained city. A giant modern sculpture and the flags of more than a dozen nations adorn its entrance, and manicured shrubbery lines its freshly paved roads. Changshu’s website lays out grand plans for the park, predicting that it “will become a paradise for technological development, a powerful treasure land and an ecologically harmonious auspicious land.”
But after more than a decade of operations, residents of a nearby village called Haiyu have planted corn between and around the neatly spaced buildings. Although the crop appears to be fed at least in part with wastewater, one of the villagers told me that people in Haiyu eat the corn as they always have, cooking it on the cob and grinding up whatever’s left to make dough for noodles.
One family of three even made their home on one of the park’s many crisscrossing canals, mooring their old wooden boat under an overpass that a plaque identified as the “DuPont Bridge.” Although the labels on the pipes lining the canal made it clear that at least some of them carried industrial waste, the family had been living there for some time, ferrying chemicals between the factories. Their boat was festooned with drying laundry.
A short drive from DuPont Bridge, a man wearing a Paddington T-shirt bearing a picture of the bear eating a sandwich was fishing in another canal. He sat under a thatch of trees across from a factory, dangling a wooden rod into the water below as brown waves lapped at the mouth of a pipe that opened onto the stone-lined canal. The man told me he worked at one of the factories. This was a Sunday, and though he didn’t have to work, he had ridden 40 minutes on his motorbike to try his luck fishing. He’s spent most of his days off this way over the past four years. And in that short time he had noticed the number and quality of the fish in the canals worsen. That morning, it had taken several hours just to catch the six small fish in the plastic bucket beside him.
Scientists might have predicted the size and yield of his catch, since PFOA has been shown to harm fish exposed to it. The chemical causes male fish to develop female reproductive cells and the ovaries of female fish to degrade. Contaminated food may account for as much as 90 percent of human exposure to PFOA and PFOS.
There are plenty of both chemicals in this water. In fact, in 2013 the scientists measured some of the highest concentrations of PFCs ever reported in China right here in this industrial park. But the man in the Paddington shirt said he wasn’t terribly concerned. He’s careful to switch fishing spots if the water begins to smell bad or turns an odd color. He had just recently stopped fishing at a nearby canal when its water turned an electric blue. He said the fish he caught at other spots sometimes tasted bad, but these were delicious, especially when stewed with soy sauce and spices over a small fire.
Ni Jiahui, director of the Changshu park, wrote in an email that wastewater in the park was pre-treated at factories and then sent to the park’s wastewater treatment plant and that factories’ exhaust systems have to pass an environmental assessment. Ni also acknowledged in his email that boats are present in the park and that people farm and fish amid the factories. “I think having people fishing and farming in the industrial park are indications that our chemicals production has not caused any problem to the environment,” he wrote. “Otherwise no one would fish here.”
Just as in the U.S., the production of PFCs in China has been followed by a rise of the chemicals in the environment — and in people. As scientists traced the growing presence of these chemicals in water and fish, they were also able to document increasing levels in human blood by looking at several students and faculty members at a university in the northern city of Shenyang. Between 1987 and 2002, the level of PFOA increased 54-fold, while blood levels of PFOS increased by a factor of 747. Since then, they have crept up further, especially in factory workers and commercial fisherman.You can also find the molecules in dust and air, as one study recently did, documenting a 12-mile plume of PFOA-contaminated air that surrounds the Dongyue plant in Shandong. The level of PFOA in the nearby Zhulong River was recently measured at 10,379 ppb, more than 148,000 times what the U.S. had deemed safe.
Yet other than guards who discouraged passing cars from slowing, nothing seemed particularly menacing about the Dongyue plant. The factory entrance was plastered with colorful billboards with reassuring English messages, such as “Safety and environmental protection are the first value of the Dongyue group,” and “Taking good care of yourself is the best love to your mother.”
Just over 5 miles away, in a small farming village called Bozhadian, the residents seemed well aware of the river’s problems. An elderly man who was ushering his herd of goats across a bridge over the Zhulong said that no one fishes in the river anymore. And the proprietor of the local corner store said simply, “The water’s not good there.”
A villager fishes in a tributary of the Zhulong River, hooking fish of only about 5 centimeters. The sign reads “Chromium Slag Remediation.”
Photo: Jiang Mei for ChinaFile/The Intercept
Low labor costs and a lack of environmental regulation helped draw American and European chemical companies to China. Since the late 1970s, when Deng Xiaoping opened the country’s economy to the world, the chemical industry has been at the heart of its dazzling growth. In the past four decades, the Chinese chemical sector has grown faster than that of almost any other country. From 2000 to 2010, production of chemicals nearly tripled. By 2010, industry sales totaled more than $754 billion a year.
Yet knowledge of the environmental hazards of industrial chemicals — and how to address them — has not always made the trip.
Since 2006, when it first negotiated the phaseout of both PFOA and PFOS in the U.S., the EPA has also required companies to drastically reduce their emissions of the chemicals. And each of the eight companies that participated readily began recycling and incinerating PFOA after using it. Companies in Japan and Western Europe also instituted recycling.
Yet in China, these straightforward techniques of disposing of PFOA appear to be the rare exception. Scientists I contacted agreed that releasing the chemical waste directly into waterways and the air seemed to be the norm. “The best available treatment technique is not used in China despite that this would be a very cost-efficient and easy way to drastically reduce emissions of PFOA,” Robin Vestegren, an environmental researcher at Stockholm University, wrote in an email.
The Dongyue Group declined a request to be interviewed for this story, but a spokesperson wrote in an email that the company denies researchers’ claims that its emissions contribute to water pollution in the Xiaoqing River. The email also said that the Chinese government has installed a 24-hour monitoring system in its factory, and that its emissions comply with government regulations. “Dongyue values environmental protection above all things,” the company spokesperson added.
But Vestegren and his colleagues in China recently calculated how much PFOA the plant would emit based on its Teflon production, and found that the number was very close to the actual amount they measured in the Xiaoqing River. (A small amount of the chemical is also emitted through the air.) Vestegren wrote that he was confident the plant “has not installed any treatment technology.”
You can even see the differences in practice between plants belonging to the same company. In the U.S., DuPont greatly reduced its emissions of PFOA after coming under scrutiny. Workers’ blood levels dropped, too. The amount of PFOA in workers at its New Jersey plant was down to an average of 1,644 ppb by 2007 and had dropped to 1,110 by 2009. But in China, the levels of PFOA in workers’ blood reached an average of 2,250 ppb within the first year of operation of the Changshu plant.
The EPA action that marked the beginning of the end of PFOA and PFOS in the U.S. might have raised red flags about the chemicals here, too. At least one Chinese news outlet, the Shanghai Star, covered the story in July 2004, when the EPA first charged DuPont with failing to report the risks of PFOA. Although it described the chemical as posing “a potential threat to health,” the Star noted that the Chinese government didn’t have the technology necessary to do its own safety tests.DuPont’s international messaging team was quick to fill in the blanks. Shortly after the news broke, two senior staff members from DuPont’s Beijing office took part in a talk show on sina.com, one of the largest Chinese-language websites, offering assurances that there was no link between PFOA and health hazards and noting that “administrative reporting requirements in the U.S.” had led to a “misunderstanding about the quality of the products.” On its Chinese website, DuPont proclaimed that the company had used the chemical “safely” for 50 years and, according to the story, that “there is no PFOA in Teflon product.”
Neither statement was true — there were trace amounts of PFOA in Teflon, and DuPont had known for years about the health effects of PFOA on its workers and lab animals. But the effort seems to have quelled any nascent controversy in China over the chemical.
In an emailed statement, a DuPont spokesperson wrote that the company “always acted responsibly based on the health and environmental information that was available to the industry and regulators about PFOA at the time of its usage.”
The driver of a Dongyue Group cargo truck cleans up rainwater from the previous night.
Photo: Jiang Mei for ChinaFile/The Intercept
Small organizations like Guo’s, which has only four full-time staff members, often rely on volunteers. More than 100 have come forward to help Green Qilu. For now, most pitch in by participating in the “black and smelly river project,” which involves visiting local waterways and reporting on whether they reek or have an odd color. The project, which is sponsored by the central government’s Ministry of Environmental Protection, has already yielded an alarming picture of the extent of water contamination nationwide. But going further — figuring out which particular contaminants are causing the changes or taking steps to remove them — is a trickier business.
Part of the problem is financial. It’s expensive to train volunteers and test water for individual chemicals. The Chinese government made a huge step in 2013 by requiring factories not only to perform certain tests on their wastewater but also to make the water itself available for independent testing. Environmentalists around the country, including Guo, have begun to collect samples. But, while more than 40,000 types of chemical products are made in China, Guo can usually only afford to test for one or two and sometimes opts for tests that simply characterize the water as good, fair, or poor.
An even bigger challenge is a fear of reprisal that hovers over environmental work in China. Businesses often don’t take kindly to citizen oversight. And if protestors are perceived as undermining the government, the consequences can be dire. Guo said Green Qilu’s volunteers wouldn’t be comfortable investigating industrial water contamination because “they’re hesitant that the factories will do something to them or their families.” And even though he is careful to file all the appropriate papers and follow all government regulations, he sometimes worries that the work will somehow cause problems for his own family.
Simply documenting levels of various substances in air, soil, and water can be a risky pursuit. Several of the Chinese researchers I spoke with who track the presence of PFOA said they didn’t want to be mentioned by name. And one environmentalist, Mao Da, told me of his difficulties finding epidemiologists to work on a survey of people living near waste incinerators. “The university professors didn’t want to do it because they didn’t want to have trouble,” Da said, adding that “data collection can be very hard because the local government may try to stop you.”
Despite the potential consequences of sticking their necks out, many have. In recent years, environmental protests have become the most common form of public demonstration, which has helped bring the country to a distinct turning point. While activists still sometimes face arrest and detention, Chinese authorities seem increasingly tolerant of their occasional outbursts and view pollution itself as a greater threat to the social order than protests over it.The country’s new environmental protection law, which went into effect last year, may be the best evidence of the seriousness with which the Chinese government is now approaching the crisis. The law lifted what had been a low ceiling on fines that government officials could impose on polluters and for the first time authorized environmental organizations to sue over pollution. The first successful verdict came in June.
The youth of the environmental movement and the severity of the mess it has sprung up to address make this an odd — and, in some ways, hopeful — moment for China. “It’s like the late ’60s in America,” said Ma Jun, director of the Beijing-based organization the Institute of Public and Environmental Affairs. “The issue is so bad and so obvious,” it’s become virtually impossible to ignore. “We feel quite lucky. It’s one of the few areas where we have so much social consensus.”
Ma has been thinking about China’s pollution problem for a long time, first as a journalist, and for the past 10 years, as head of the venture that came up with perhaps the cleverest way to fix it. To Ma, the most vexing aspect of China’s situation was the lack of transparency. Large companies throughout the world had outsourced their dirty chemical work to China, but few were keeping track of what these companies were doing with their waste. The big foreign companies sometimes didn’t even know which companies were supplying their chemicals, let alone what their environmental practices were. “The supply chain was a black box,” said Ma.
IPE has managed to shine light into that box by harnessing both the Chinese government’s amped up commitment to tracking pollution and the internet’s power for public shaming. The organization created a database that allows multinational and local brands to see whether their Chinese suppliers comply with the law, using data that factories are now obligated to report about their waste. It also synthesized information on companies such as Adidas, H&M, Zara, and Dell — whether they screen their suppliers or even attempt to identify pollution problems, for instance — into handy online charts available in English.
Unfortunately, IPE’s online tool has very little information on PFOA or PFOS, since reporting on the use of these chemicals is still voluntary. But you can get a sense of some of the companies that still use these chemicals from the EPA’s website.
A wastewater discharge site near the Zhulong River. The signs read “Danger: Discharge Site with Deep Water. Take Caution.”
Photo: Jiang Mei for ChinaFile/The Intercept
In some cases, the rationale for requesting an exemption seemed to be based on the unique qualities of PFCs. (PFOA gives ski racers an inimitable glide, for instance.) But for many manufacturers, the challenge appeared to be logistical. A letter from the Association of Global Automakers described the average car as “a complex web of systems and networks, containing more than 30,000 unique components sourced from thousands of suppliers around the world.” Thus, it concluded, removing the chemicals would pose “significant challenges to the automotive sector.”
A villager living in Dongba village outside Zibo, Shandong, raises sheep for a living near a chemical plant owned by the Dongyue Group.
Photo: Jiang Mei for ChinaFile/The Intercept
But even with the backing of 179 countries, including China, the Stockholm Convention has made slow progress. The convention added PFOS to the list of substances to be restricted in 2009. Implementation of the order didn’t begin until 2014. Even then, industries petitioned for exemptions, and loopholes were carved out for the use of PFOS in firefighting foam, liquid crystal displays, color printers, and decorative plating. A precursor of PFOS can still be used to control red fire ants, and China ships between 30 and 50 tons of it each year to Brazil, which has used and then dumped much of the stuff.
When I visited the office responsible for implementing the Stockholm Convention in China, on the outskirts of Beijing, the staff had recently finished hosting a delegation from North Korea. To put the enormity of their burden in some perspective, they had been coaching the North Koreans on how to eliminate PCBs, chemicals the rest of the world stopped making decades ago. In addition to overseeing the Stockholm Convention project throughout the Pacific region, which includes many countries that are much further behind in terms of eliminating the chemicals than China, the office is also responsible for administering the Basel Convention, a separate treaty governing the transnational movement of hazardous waste.
All of which helps explain why their efforts to reduce PFOS in China through the convention are just getting underway. “We’re just in the beginning to investigate how much of the chemical occurs,” one staff member told me. “China is a very big country. We have a lot of industry. We need some time.”
In the coming weeks, a committee is expected to take the first steps toward adding PFOA to the convention’s list. Though participating governments probably won’t make a final decision until at least 2019, it seems likely that at some point not too far in the future, that chemical, too, will start inching closer to elimination.
This is often how things work for toxic leftovers; as constraints on them grow, many chemicals wind up coming to China just to die a slow death.“The country may get a few years out of it,” IPEN’s DiGangi said of PFOS, which itself was a substitution for another chemical, Halon, that was produced in China and phased out in the 1980s because it was depleting the ozone layer. For the PFCs, foreign companies have already taken the next step, replacing PFOA and PFOS with similar molecules that are based on shorter-carbon chains. DuPont, for instance, swapped out PFOA for a chemical it calls GenX.
Indeed, Ni Jiahui, the director of the Changshu industrial park, said that because of safety concerns, both PFOS and PFOA have now been replaced with shorter-chain PFCs. The most recent testing, done in 2012, showed both these replacement molecules and PFOA were present in the water around the park.
While new testing could help clarify that the park has since exclusively switched to shorter-chain replacements such as GenX, it’s difficult to confirm whether companies have phased out chemicals. For instance, one group of German scientists led by Franziska Heydebreck recently measured extremely high levels of 8- and 10-carbon chain compounds inside a Chinese textile manufacturing plant that supposedly had switched to shorter-chain replacement PFCs.
Because many of the shorter-chain PFCs do not appear to be much safer than PFOA and PFOS, even if companies do switch to these molecules, they will likely wind up having to swap out these replacements as they are targeted for global elimination.
The justification for adopting these cast-off chemicals is financial, of course. Yet, many of the leftovers that were big moneymakers in their earlier years aren’t as lucrative in the last stage of their lives. As China has become the main producer of Teflon in recent years, its price has dropped.
Whether because of this or the broader economic forces that have squeezed the Chinese chemical industry, business was slow for the family living on the boat under DuPont Bridge. In the past month, the woman said, she had ferried only a single load of chemicals over the canals of the Changshu industrial park and was worried about how her family would survive.
A few miles away, in a hotpot restaurant in the small city of Fushan, two men also pondered the business of making a living at the chemical park. The name “Fushan” translates to “Fortune Mountain.” But given its proximity to the factories that make PFCs, some locals have darkly joked that the town ought to be called “Fluorochemical Mountain,” which sounds very similar in Chinese.
A couple waits on the Fushan River for assignments transporting chemicals.
Photo: Jiang Mei for ChinaFile/The Intercept
The argument briefly grew heated, as the two men raised their voices and put down their chopsticks. But the factory worker put an end to it with an analogy: “It’s like walking down the road,” he said, as they returned to their meal. “There’s always a chance you might get hit by a bus, but still you walk.”
The analogy doesn’t hold up. China faces far more than the possibility that these toxic chemicals will spread throughout the country. They already have, exposing Chinese people to PFCs without their knowledge or consent. It’s much the same predicament Americans were in 15 years ago, except that this time scientists have a far greater understanding of the dangers posed by the molecules being released into water and soil. And even as international experts prepare to hammer out which chemicals to tackle next and the Chinese government slowly brings its immense power to bear on the pollution problem, they continue to accumulate.
Back in Cuijia, the situation is already urgent. According to Wu, young people in the village decided their best shot — the only one in their power, really — was to leave. Most have. Not long ago, Wu’s own son set off to become an itinerant worker, a life he hopes will be safer than relying on the polluted Xiaoqing River.
This article was reported in partnership with The Investigative Fund at The Nation Institute and ChinaFile.
Research: Coco Liu

When the U.S. phased out PFOA, long used to make Teflon, China's production and use of the toxic chemical soared.











I see Wnt’s point about the fluorine atoms in PFOAs seeming to not exert its influence in the ‘usual’ way fluorine does, since the molecule is so stable. However, there are ways it can be defluorinated/degraded, certainly outside the body and I would imagine inside the body as well. This process could indeed liberate some of those fluorine atoms. Some researchers are using UV light plus one of the methods the body uses to produce free radicals (the Fenton reaction) to defluorinate/biodegrade PFOA in water supplies. It could be that if/when PFOA gets defluorinated in the body, then that would free up some of the fluorine atoms to cause great harm.
I tried finding out definitively from the literature the way the molecule, PFOA—and PFCs in general–can be so toxic in so many ways but it doesn’t seem to be known at this stage. A comprehensive article, which is available for free (unlike most science journal articles) is “Toxicology of Perfluorinated Compounds” in the journal, Environmental Sciences Europe (http://enveurope.springeropen.com/articles/10.1186/2190-4715-23-38)
Interestingly, even though PFCs are not fat soluble some of them nevertheless have elimination half-lives measured in years in humans!
PFOA is “a carcinogen, a liver toxicant, a developmental toxicant, and an immune system toxicant, and also exerts hormonal effects including alteration of thyroid hormone levels. Animal studies show developmental toxicity from reduced birth size, physical developmental delays, endocrine disruption, and neonatal mortality”…..PFOA has been detected in the blood of more than 98% of the general US population in the low and sub-parts per billion range, and levels are higher in chemical plant employees and surrounding subpopulations. … PFOA has been detected in industrial waste, stain resistant carpets, carpet cleaning liquids, house dust, microwave popcorn bags, water, food, some cookware and PTFE such as Teflon”. (Wikipedia)
People who consume the highest levels of fish have the highest levels of PFCs and there are many other sources, including microwave popcorn. “After heating, the PFOA concentration in the popcorn itself was about 300 ?g/kg (note: a tremendous amount). PFOS concentrations… were detected in potatoes, canned vegetables, eggs, sugar, and preserves. Particularly striking was the group of potato products, where in addition to PFOD, PFOA and 10 other PFCs were detected…. No foods that have been examined to date other than fish were found to have a level of contamination great enough to result in reaching the Tolerable Daily Intake (TDI) for PFOS or PFOA, assuming realistic consumed amounts. Nonstick cooking utensils contribute less to PFC exposure to food than coated papers or cardboard boxes. The US Food and Drug Administration [FDA] named coated paper as the largest possible source of fluorochemicals. According to the FDA, nonstick frying pans are, by comparison, an insignificant source of PFCs (note: ‘coated paper’ are the wrappers fast food comes in, which is why fast food can be so high in these compounds). Other sources are jackets, trousers, shoes, carpets, upholstered furniture, cleaning agents, household dust and indoor air. (“Toxicology of Perfluorinated Compounds”)
Diet is by far the greatest source of PFCs.
‘300 ?g/kg’ should be 300 mcg/kg
Interesting article but some factual errors/exaggerations. Eg, “More than 80 percent of China’s underground water supply is unfit for human consumption…” – data is not from a nationally representative survey, as stated in the source cited in the article: “…the ministry conducted a survey of 2,103 water wells in the northeast, north, northwest, and central parts of China”. FYI
Thanks for this and the others very accurate previous articles on PFOA. Among the Western countries with drinking water contaminate from PFOA and other PFAS you should add Italy too, In fact the Government of the Veneto region, in the northeast of the country ,in the summer of 2013 announced that approximately 3000,000 residents in 60 municipalities had been drinking , for over four decades, water contaminated with PFOA and other PFAS by an industry owned by Mteni of Trissino, in the province of Vicenza. The authorities didn’t suspended the provision of public water, but applied filters and diluted the contaminated water with non-contaminated one, so reducing the levels of many PFAS to values below the limits that were established later, in 2014: PFOS <30 ng / L, PFOA <500 ng / L, PFBA 3000 ng / L, PFBS <3000 ng / L, other PFASs <500 ng / L). In Italy there are no protective enforceable limits to human health, as in the rest of the world, so that the industry that has polluted will never pay for the damage caused to the environment and to humans. Recently, two epidemiological studies have indipendently shown an excess of mortality in the years 1980-2014 (30-40 deaths for year in excess) for diabetes, acute myocardial infarction, stroke, hypertension and kidney cancer and an increased prevalence of hypothyroidism and hypercholesterolemia in the most contaminated areas compared to the regional means.
The chemical corporations have a trade organization that has a long history of eliminating local control over the use of their products. Through state legislation they have stripped cities and counties of the ability to legally regulate chemicals toxic or otherwise deployed in their environments. Now they are moving this effort to the national and international level thus stripping sovereignties of control, just as they recently preempted the Vermont law on GMO labelling. Now in the works too are international trade treaties that will preempt national controls. Things like France’s outlawing retail sales of glyphosate would / will be considered restraint of trade with the offender fined into compliance. If these corporations get their way there will be no place on earth you can hide from the toxic nightmare that this article describes.
If it gets past the feds’ anti-trust concerns, which remains to be seen, this happened 2 days ago:
http://www.npr.org/sections/thetwo-way/2016/09/14/493896473/chemical-giant-bayer-agrees-to-buy-monsanto-for-66-billion
This has been a great series, even for as distressing as the subject matter is. Bravo to the author and the Intercept. This is the kind of reporting I want to read here…not social justice warrior or blame-everything-on-evil-USA crap.
BTW: I had occasion to be in China for an extended period for work several years ago, and it was one of the most disgusting, polluted, horrible places I’ve ever been to. In fact, it was the only country in my extensive travels that I could not wait to flee from as soon as possible. Even a chance to spend a night in Macau walking around that circular shopping mall couldn’t keep me anywhere near the PRC one day longer than necessary. So gross.
I would like to see more clarity on how these “free trade agreements” affect this. While I suppose simply banning Chinese PFOA would be prohibited by them, would they really prohibit a system of inspection? I mean, I know the USDA has inspectors abroad, for example. So could producers of Teflon, wherever they are, be required to certify the PFOA was recycled, subject to inspections?
It is obvious that offshoring PFOA is a lose-lose for America and the Chinese ecology also. It doesn’t seem to me like American politicians give a damn about trade; they always seem eager to just send something offshore simply because they don’t like it (like butchering horses, for example). So it’s informative to know what sovereignty they’ve already given up and what they just don’t feel like exercising.
Ya know, I was very interested in this article when I read the headline. But when I clicked on it I saw that it was really long, and when I read the beginning I saw that it was another of these obnoxious NPR-style stories. If I want to read a book, I’ll buy one or go to the library. These articles need to be succinct, not meandering BS that seems like their function is more to boost the writer’s ego than to tell about the subject. Guess what? Most of us have other things to do than read needlessly long articles.
jesus.
The sign did not say “chromium slag mediation”.
Good point, what is with that caption?
Right, the sign reads:
Fushan City Government reminds you:
hazardous water depth
exercise caution
the rothschild zion criminal currency monopoly in the US is based on escalating rate of population increases which will destroy the planet.
may you live in interesting times
OMG! Solid environmental reporting is back on the internet again. I got through about half the story and will finish later. So far so good. Sadly, much of the lessons learned on pollution control were ignored as industry went east. Now China seems to be looking at hundreds of billions and maybe trillions of dollars for soil and groundwater remediation.
http://siteresources.worldbank.org/INTEAPREGTOPENVIRONMENT/Resources/China_Cost_of_Pollution.pdf
That estimate could be less if China picks up on a remediation technique called “risk it away” – where the human health risk of the chemical in the environment is deemed not all that risky if one avoids the environment. Sort of a joke, sorry. Anyway here’s a paper along the lines of cleaning up the mess discussed in the excellent report above. It’s an academic study – not an environmental consultant business development plan, I’m assuming
“China’s Soil and Groundwater Remediation Challenges: Lessons from UK’s Experience and Opportunities in China.”
https://www.researchgate.net/publication/297721105_China's_soil_and_groundwater_management_challenges_Lessons_from_the_UK's_experience_and_opportunities_for_China
The capitalists love the communist Chinese, don’t they?
Thank you for this excellent article. ‘Pollution’ was more of an abstract concept to me as a Westerner until I got to live in S.E. Asia and thereby experience the toxic nightmare that has befallen so many ‘developing’ countries. I try to explain it to my Western friends who have never been to this part of the world, but it is not easy to understand this unless one has actually experienced the lungs wheezing, the sick and desperate days of feeling so ill you don’t want to move around much, as if some…thing… has taken hold of your cellular machinery and made it start to grind and tear itself apart. I find that all of the locals don’t ‘notice’ the pollution because, I believe, this is all they have ever known and so this is ‘normal’ to them. I try and describe what a breath of fresh air tastes and feels like, but of course you can’t really describe such a thing.
“perfluorooctanoic acid, or PFOA…”
the ‘perfluoro’ means a compound in which every hydrogen atom has been replaced by fluorine.
“Fluorine …..exists as a highly toxic pale yellow diatomic gas at standard conditions. As the most electronegative element, it is extremely reactive…” (Wikipedia)
“Extremely reactive” means, among other things, that it can ‘attack’ other molecules, ripping electrons from them, thereby oxidizing them and often changing them for the worse (for living creatures). “Fluorine is such a strong oxidizer that it produces the highest oxidation states in nature”. (‘Fluorine’ by Tom Jackson)
I wouldn’t be surprised if the ‘C8’ (8 carbon atoms) moniker was given to it by a PR person, because more noteworthy–from a toxicological perspective—is that the molecule has 15 fluorine atoms.
It should be called F15 instead.
You’re kind of barking up the wrong tree there. Fluorine is incredibly reactive, but once it’s reacted, it doesn’t want to give up its prize. What makes Teflon so untouchable, what makes PFOA so enduring in the body and the environment, is that the fluorines stuck to the carbon backbone won’t go anywhere. Neither the body nor the environment have any particularly effective ways of breaking down the resulting fluorine-armored molecule.
I have a strong feeling that the Chinese govt. cares more for its people than our government,and yes,their industrial development,at Americas expense and gift,has created environmental issues.
But I guarantee they will keep up with their problems better than we do,as looking at their infrastructural miracles reveals.
From the Pearl River,to bridges in the sky,incredible.
“Chinese govt. cares”
Yes, that’s why they force companies to put nets around the dormitories of their forced labor camps so employees can’t jump from high floors in attempts to commit suicide.
It’s exactly because they care……right.
What a joke.
http://www.chinalaborwatch.org/report/109
https://www.wired.com/2015/04/inside-chinese-factories/
How China is Screwing Over Its Poisoned Factor Workers
Great article, and I’d add on this:
The free trade agreements have had a large effect on this as well; tariff reductions and laws banning restrictions on trade over environmental and labor issues allow chemical companies to outsource to China and India and Mexico with no significant costs to themselves.
The sad things is, even if Teflon-type products are an industrial necessity, by better design of chemical processes and waste treatment it’s possible to manufacture them without polluting rivers and groundwater and air – but the chemical production plant needs essential another plant, of similar cost, on the end to process all the waste (i.e. breaking down the carbon-flourine waste molecules into flouride salts, which are much less harmful, and can be recycled back into the front end of the process).
It is encouraging to see that China now has a pollution law that allows environmental groups to sue; such laws were passed in the United States in the 60s and 70s in the wake of Rachel Carson’s Silent Spring, which is still highly recommended reading (it focuses mainly on the organochlorine compounds and organophosphates used as biocides in agriculture for pest control):
https://www.youtube.com/watch?v=hDicpd4Ry8E
Photos of the air in China: depressing. But, hey, they have jobs right? And now maybe all the cookware (even those made in USA) will be coated with chemicals from China. Great news.
So what is the soln? Use only carbon or stainless steel cookware w/o coating? But where does the steel come from? China? And how is steel made? Ooof, yikes.
Wondering if it’s possible to have clean mfg? Could a person get the atoms/molecules of some object to arrange themselves in to shapes that take so much energy and effort now? Say a pine 2×4 — instead of cutting down a tree and stripping everything, grow it as a 2×4… and a steel pot, would it be possible to do the same thing using less energy and less material waste and no “pollution”?
History just repeats itself here. Look at Donora Pa; they used have jobs prior and up to 1948-9 until the zinc smelting plant w/ ‘mother earth’ conspired and killed a bunch of the folks in that town. So, go to Donora now, I’d bet there may be a Walmart there… and I’d bet they sell goods made in China.
Really what is the soln here? Malthusian? Abandon tech all together?
Last time I worked in Donora the word was “Plastics”
There was an innertube race down the river.
The hotel had a sports museum showing the really incedible number of great local atheletes produced there.
Sure you can have clean chemical manufacturing but your costs are going to go up by around 50%, beacuse on the back end of your chemical manufacturing system, you need to build a waste treatment system that breaks all the nasty molecules down to safe forms. If you strip all the flourine atoms off the waste molecules, you convert them to salts, which are basically much less toxic; compare organochlorine PCBs or dioxin to sodium chloride, NaCl, table salt.
But, what happens is that if one company acts responsibly and builds a waste treatment system, its costs rise and the product cost has to double; so a competitor can put them out of business by dumping all the waste into a river and selling at half the price. This is why we NEED government regulation, so that all companies have to meet the same standard; the ‘free-market economists’ who call for deregulation are thus calling for massive pollution of air and water, in our industrialized society.
It’s the same concept that applies to human excrement – if all the toilets flushed right into rivers, they’d be full of turds, especially around cities with lots of human beings. Eventually, the notion of sewage treatment plants to break down all the excrement (organic carbon) to carbon dioxide, with the help of bacteria and mechanical systems, caught on and cities started discharging pretty clean water into rivers, vastly cutting down on diseases like cholera and dysentery. But wastewater treatment plants cost a lot of money; millions for small towns and billions for big cities, and people have to agree to build and pay for them.
I appreciate that; hope your background is chemical.
It’s true regulation is needed; but it’s really not working. You’re just pushing the pollution to a third world or an economy that is willing to suffer the env cost in exchange.
Maybe it’ss US regulation along w/ not allowing US companies to source outside to other companies w/o regulation? Also would the US need to ban imports from countries where env. reg is lax?
Disregard, should have read your post above..
That’s why decent trade rules would ban the import of products made with sub-par pollution and labor standards in sweatshop zones, or at least apply very high tariffs; in contrast, the kind of trade deals championed by the U.S. deliberately outlaw such efforts.
Very informative report, thanks.
By the way I would be careful with the finished product too.
Even the tobacco companies were extremely careful that no machinery contained Teflon parts because when you burn it bad decomposition products are produced.
https://www.fluoridealert.org/wp-content/pesticides/teflon.decomposition.prod.htm